The first TDDFT and MCD studies of free base triarylcorroles: a closer look into solvent-dependent UV-visible absorption.
نویسندگان
چکیده
Absorption spectra of several free base triarylcorroles were investigated by MCD spectroscopy. The MCD spectra exhibit unusual sign-reverse (positive-to-negative intensities in ascending energy) features in the Soret- and Q-type band regions, suggesting a rare ΔHOMO < ΔLUMO relationship between π and π* MOs in the corrole core.
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ورودعنوان ژورنال:
- Chemical communications
دوره 48 39 شماره
صفحات -
تاریخ انتشار 2012